A GO/CoMo₃S₁₃ Chalcogel Heterostructure with Rich Catalytic Mo–S–Co Bridge Sites for the Hydrogen Evolution Reaction

Molybdenum disulfide (MoS₂)-based materials are extensively studied as promising hydrogen evolution reaction (HER) catalysts. In order to bring out the full potential of chalcogenide chemistry, precise control over the active sulfur sites and enhancement of electronic conductivity need to be achieved. This study develops a highly active HER catalyst with an optimized active site-controlled cobalt molybdenum sulfide (CoMo₃S₁₃₎ chalcogel/graphene oxide aerogel heterostructure. The highly active CoMo₃S₁₃ chalcogel catalyst was achieved by the synergetic catalytic sites of [Mo₃S₁₃]²⁻ and the Mo–S–Co bridge. The optimized GO/CoMo₃S₁₃ chalcogel heterostructure catalyst exhibited high catalytic HER performance with an overvoltage of 130 mV, a current density of 10 mA cm⁻², a small Tafel slope of 40.1 mV dec⁻¹, and remarkable stability after 12 h of testing. This study presents a successful example of a synergistic heterostructure exploiting both the appealing electrical functionality of GO and catalytically active [Mo₃S₁₃]²⁻ sites.