Oleg Yazyev1
Ecole Polytechnique Federale de Lausanne1
Oleg Yazyev1
Ecole Polytechnique Federale de Lausanne1
Layered transition metal dichalcogenides (TMDs) of chemical composition <i>MX</i><sub>2</sub> (<i>M</i> = transition metal; <i>X</i> = S, Se, or Te) represent a broad family of materials with diverse electronic properties, including metals, insulators, as well as more complex states such as the charge-density-wave (CDW) and superconducting phases. More recently, the possibility of realizing single- and few-layer TMDs has brought the two-dimensional (2D) forms of these materials into the spotlight of prospective application in electronics, optoelectronics and beyond [1]. In my talk, I will review the “periodic table” of TMDs attempting to reveal systematic trends and develop chemical intuition across this family of 2D materials. Using a Wannier function approach, I will address the relevance of the crystal and ligand fields in determining the relative stability of 1T and 1H polymorphs as a function of the filling of the d-shell in 2D TMDs [2]. Then, I will present a unified picture of lattice instabilities in metallic TMDs that describes both the CDW phases and the strong-coupling scenario resulting in the formation of metal-metal bonds (as e.g. in the dimerized 1T’ phases) [3]. In the rest of my talk, I will focus on topological and magnetic phases of TMDs. The 1T’-phase of Mo and W TMDs that have recently been shown to host the topologically non-trivial quantum spin Hall (QSH) insulator phase. The robustness of the QSH phase as well as the topological edge states [4] and interface states at the well-ordered 1T’-1H lateral heterojunctions will be discussed in conjunction with recent experiments on 1T’-WSe<sub>2</sub> [5]. I will also cover our recent discovery of magnetic ordering and magnetoresistive switching in metallic few-layer and insulating single-layer PtSe<sub>2</sub> [6,7]. <br/><br/>1. S. Manzeli, D. Ovchinnikov, D. Pasquier, O. V. Yazyev and A. Kis, Nature Rev. Mater. <b>2</b>, 17033 (2017).<br/>2. D. Pasquier and O. V. Yazyev, 2D Materials 6, 025015 (2019).<br/>3. D. Pasquier and O. V. Yazyev, Phys. Rev. B <b>100</b>, 201103(R) (2019).<br/>4. A. Pulkin and O. V. Yazyev, J. Phys. Chem. Lett. <b>11</b>, 6964 (2020).<br/>5. M. M. Ugeda <i>et al.,</i> Nature Commun. <b>9</b>, 3401 (2018).<br/>6. A. Avsar <i>et al.</i>, Nature Nanotechnol. <b>14</b>, 674 (2019).<br/>7. A. Avsar <i>et al.</i>, Nature Commun. <b>11</b>, 4806 (2020).