Nikhil Sharma1,Kejie Zhao1
Purdue University1
Nikhil Sharma1,Kejie Zhao1
Purdue University1
Nickel manganese cobalt oxides (NMC) are state-of-the-art cathode materials for Li-ion batteries. The layered lattice structure of NMC exhibits highly anisotropic strains upon Li intercalation, leading to particle fracture and interfacial delamination of the active particles from the conductive matrix. Such mechanical degradation becomes a crucial issue in pursuing high Ni-content and Co-free cathodes. Notably, the experimental information regarding the anisotropic mechanical properties of NMC cathodes is missing in the literature. In this study, we measure the stiffness constants of single crystalline NMC cathodes using environmental nanoindentation. The correlative measurements of the elastic stiffness and the lattice orientations allow us to fully determine the stiffness matrix. Furthermore, we compare the effective elastic indentation modulus, hardness, and fracture toughness of different NMC compositions. The complete information on the mechanical properties of NMC cathodes will enable accurate computational modeling and assist in designing and manufacturing durable rechargeable batteries.