Pierfrancesco Ombrini1
Delft University of Technology1
Pierfrancesco Ombrini1
Delft University of Technology1
Phase separation during the lithiation of redox-active materials is a critical factor affecting battery performance, including energy density, charging rates, and cycle life. Accurate physical descriptions of these materials are necessary for understanding underlying lithiation mechanisms, performance limitations, and optimizing energy storage devices. This work presents an extended regular solution model that captures mutual interactions between sublattices of multi-sublattice battery materials, typically synthesized by metal substitution. We apply the model to phospho-olivine materials and demonstrate its quantitative accuracy in predicting the composition-dependent redox shift of the plateaus of LiMn<sub>y</sub>Fe<sub>1-y</sub>PO<sub>4</sub> (LFMP), LiCo<sub>y</sub>Fe<sub>1-y</sub>PO<sub>4</sub> (LFCP), LiCo<sub>x</sub>Mn<sub>y</sub>Fe<sub>1-x-y</sub>PO<sub>4</sub> (LFMCP), as well as their phase separation behavior. Furthermore, we develop a phase-field model of LFMP that consistently matches experimental data and identifies LiMn<sub>0.4</sub>Fe<sub>0.6</sub>PO<sub>4</sub> as a superior composition that favors a solid solution phase transition, making it ideal for high-power applications.