MRS Meetings and Events

 

EN02.03.26 2023 MRS Fall Meeting

Innovative Gel Polymer Electrolyte for Safe and Long-Lasting Active Implantable Medical Devices

When and Where

Nov 27, 2023
8:00pm - 10:00pm

Hynes, Level 1, Hall A

Presenter

Co-Author(s)

Mike Molinski1,Hailey Simon1,Brian Chiou2,Arijit Bose2

Audiance, Inc.1,University of Rhode Island2

Abstract

Mike Molinski1,Hailey Simon1,Brian Chiou2,Arijit Bose2

Audiance, Inc.1,University of Rhode Island2
Active implantable medical devices (AIMDs) play a pivotal role in modern healthcare, offering advanced therapeutic solutions for a variety of medical conditions. The power sources within them play a critical role and have demanding performance attributes, namely high energy density, long-term reliability, and exceptional safety. Primary lithium-ion batteries have emerged as a popular choice due to their high energy density, predictable performance, and long cycle life. However, their implementation in AIMDs faces certain limitations, primarily concerning safety considerations as novel more capable devices demand higher battery capacities. AUDIANCE has developed an innovative safe, stable, and non-flammable gel polymer electrolyte (GPE) that address the limitations of current lithium-ion battery technologies and unlocks the potential for use of rechargeable or secondary lithium-ion batteries in AIMDs.<br/><br/>Consisting of a carrier, a high molecular weight polymer, and a conductive lithium salt, the GPE exhibits excellent lithium-ion conductivity of 2.58 x 10<sup>-3</sup> S/cm at 37°C and demonstrates a wide electrochemical stability window with a polymer decomposition voltage of about 4.2V. Notably, the mechanical properties of the high viscosity electrolyte are highly composition-dependent, which enables precise control over its rheology, facilitating processability and preventing electrolyte leakage while infiltrating electrode pores. Extensive safety testing has validated the reliability of AUDIANCE's technology. In flammability tests, the electrolyte self-extinguishes, ensuring enhanced safety even during catastrophic failure events. Moreover, nail penetration, overcharge, and external short circuit tests conducted on cells fabricated with the GPE resulted in minimal temperature change and no gas emissions. Long-life cycle testing of LTO|LFP cells demonstrated negligible capacity loss over 4,750 cycles at 37°C, underscoring the stable electrochemical performance and prolonged lifespan of AUDIANCE's batteries.<br/><br/>The outcomes of this research present a promising pathway towards safer and more efficient power sources for AIMDs. The utilization of the novel GPE holds the potential to enhance the reliability and longevity of implantable medical devices, paving the way for novel therapeutic interventions and improving the quality of life for countless patients worldwide.

Keywords

polymer

Symposium Organizers

Yi Lin, NASA Langley Research Center
Fang Liu, University of Wisconsin--Madison
Amy Marschilok, Stony Brook University
Xin Li, Harvard University

Symposium Support

Silver
BioLogic
Verder Scientific, Inc.

Session Chairs

Xin Li
Fang Liu

In this Session

EN02.03.01
Database Driven Solid-State Electrolyte Material Search for Li and Na-Metal

EN02.03.02
Elucidating Differences in Surface and Bulk Properties of Solid-State Electrolytes

EN02.03.03
Investigating Different Solvents for Liquid Phase Synthesis Routes of Lithium Indium Chloride Solid Electrolyte for Solid-State Batteries

EN02.03.04
Effect of Lithium Precursor on the Crystal Structure and Ionic Conductivity of Li7La3Zr2O12 Oxide Electrolyte

EN02.03.05
A Highly Conductive and Stable Ionic Liquid Gel Electrolyte for Calcium Metal Batteries

EN02.03.06
Improving Lithium-Ion Conductivity by Co-Doping Al/Ta to Li7La3Zr2O12 using Molten Salt Synthesis Method

EN02.03.07
LiPON Layer Effect for Reduction of Interfacial Resistance of LLZO/Li for All-Solid-State Battery

EN02.03.08
Ultrathin Sulfide-Based Composite Electrolyte Membrane for Solid-State Sodium Metal Batteries

EN02.03.09
Epoxy Resin Based Solid Electrolyte for Multifunctional Structural Batteries

EN02.03.11
Li+ Conduction Mechanism in Anion-Substituted Halide Solid Electrolytes for All-Solid-State Batteries

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