Nageh Allam1
American University in Cairo1
Nageh Allam1
American University in Cairo1
Rational design and structural regulation of hybrid nanomaterials with superior electrochemical performance are crucial for developing sustainable energy storage platforms. Among these materials, NiCo-layered double hydroxides (NiCo-LDHs) demonstrate an exceptional charge storage capabilities owing to their tunable 2D lamellar structure, large interlayer spacing, and rich redox electrochemically active sites. However, NiCo-LDHs still suffer from sever agglomeration of their particles with limited charge transfer rates, resulting in an inadequate rate capability. In this study, bimetallic ZnCo-metal organic framework (MOF) tripods were grown on the surface of NiCo-LDH nanowires, which significantly reduced the self-agglomeration and stacking of the NiCo-LDH nanowire arrays, offering more accessible active sites for charge transfer and shortening the path for ion diffusion. The fabricated hybrid ZnCo-MOF@NiCo-LDH and its individual counterparts were tested as supercapacitor electrodes. The ZnCo-MOF@NiCo-LDH electrode demonstrated a remarkable specific capacitance of 1611 F g<sup>–1</sup> at 2 A g<sup>–1</sup> with an enhanced rate capability of 66% from 2 to 20 A g<sup>–1</sup>. Moreover, an asymmetric all solid-state supercapacitor device was constructed using ZnCo-MOF@NiCo-LDH and palm tree-derived activated carbon (P-AC) as positive and negative poles, respectively. The constructed device can store a high specific energy of 44.5 Wh Kg<sup>–1</sup> and deliver a specific power of 876.7 W Kg<sup>–1</sup> with outstanding Columbic efficiency over 10,000 charging/discharging cycles at 15 A g<sup>–1</sup>.