MRS Meetings and Events

 

EN07.10.03 2022 MRS Fall Meeting

Ni-Foam-Graphene-CNTs-SnSeP—An Efficient Electrocatalyst Covering Universal pH Range and Tap Water Splitting for Hydrogen Evolution Reaction

When and Where

Dec 6, 2022
1:30pm - 1:45pm

EN07-virtual

Presenter

Co-Author(s)

Mansi Pahuja1,Kehkashan Alam1,Kaushik Ghosh1,SK Riyajuddin1

INST Mohali1

Abstract

Mansi Pahuja1,Kehkashan Alam1,Kaushik Ghosh1,SK Riyajuddin1

INST Mohali1
A day-by-day boost in the hunger of people for renewable energy has to be addressed where green fuel generation via water splitting is a game changer to fossil fuels. The development of rationally designed cost-effective noble-metal free electrocatalyst with high efficiency, and long-term stability has been vigorously pursued. Herein, we report a super- hydrophilic bi-ligand metal phosphide (SnSeP) on the surface of a highly porous Nickel foam-graphene-carbon nanotubes matrix via the facile thermal Chemical Vapour deposition method. The newly developed electrocatalyst renders superior electrocatalytic performance with long-term stability for a minimum of 10 days at a high current density of 250 mA/cm<sup>2</sup> in each acidic, basic and neutral medium, inferring the commercialization of the catalyst toward industrial-grade application. The excellent electrocatalytic performance is analyzed in terms of low overpotential of 45 mV, 85 mV, and 135 mV at 10 mA/cm<sup>2</sup> in acidic, basic, and neutral media respectively. Moreover, the as-designed catalyst has shown a noteworthy performance in the smart utilization of tap water in hydrogen fuel production. This work highlights a new insight in adopting a feasible strategy to develop a cost-effective robust electrocatalyst that is capable enough for the facile usage of tap water that could be an attractive paradigm of green fuel synthesis via renewable electrochemical energy conversion.

Keywords

graphene

Symposium Organizers

Alexander Headley, Sandia National Laboratories
Mitch Ewan, University of Hawai'i
Thomas Gennett, National Renewable Energy Laboratory/Colorado School of Mines
Samantha Johnson, Pacific Northwest National Laboratory

Publishing Alliance

MRS publishes with Springer Nature