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Fall 2008 Logo2008 MRS Fall Meeting & Exhibit

December 1-5, 2008 | Boston
Meeting Chairs:
 S. Ashok, Shenda M. Baker, Michael R. Fitzsimmons, Young-Chang Joo

Symposium S : Solid-State Ionics

2008-12-01   Show All Abstracts

Symposium Organizers

Enrico Traversa University of Rome Tor Vergata
Timothy Armstrong Carpenter Technology Corporation
Koichi Eguchi Kyoto University
M. Rosa Palacin Institut de Ciencia de Materials de Barcelona (CSIC)
S1: Micro SOFCs: From Materials to Devices
Session Chairs
Tim Armstrong
Enrico Traversa
Monday PM, December 01, 2008
Back Bay A (Sheraton)

9:30 AM - **S1.1
Investigation of Cathode Behavior of Model Thin Film SrTi1-xFexO3-δ Mixed Ionic-Electronic Conducting Electrodes.

Harry Tuller 1 , WooChul Jung 1
1 Materials Science & Engineering, MIT, Cambridge, Massachusetts, United States

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10:00 AM - S1.2
Local Electronic Structure and Surface Chemistry of Solid Oxide Fuel Cell Cathodes.

Bilge Yildiz 1 , Burc Misirlioglu 1 , Richard Schalek 2 , Balasubramaniam Kavaipatti 3 , Paul Salvador 3
1 Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, United States, 2 Center for Nanoscale Systems, Harvard University, Cambridge, Massachusetts, United States, 3 Materials Science and Engineering, Carnegie Mellon University, Pittsburgh,, Pennsylvania, United States

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10:15 AM - S1.3
In situ Characterization of Equilibrium Strontium Surface Segregation in Epitaxial La0.7Sr0.3MnO3 at Solid Oxide Fuel Cell Conditions.

Tim Fister 1 , Matthew Highland 1 , Marie-Ingrid Richard 1 , Dillon Fong 1 , Jeffrey Eastman 1 , Peter Baldo 1 , Paul Fuoss 1 , Kavaipatti Balasubramaniam 2 , Joanna Meador 2 , Paul Salvador 2
1 Materials Science Division, Argonne National Laboratory, Argonne, Illinois, United States, 2 Materials Science and Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania, United States

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10:30 AM - S1.4
Application of Nanoscaled LSC Thin Film Cathodes in SOFCs: FEM Modelling and Experimental Verification.

Jan Hayd 1 , Ellen Ivers-Tiffee 1 , Bernd Rueger 1 , Uwe Guntow 2
1 Institute of Materials for Electrical Engineering (IWE) , Universität Karlsruhe (TH), Karlsruhe Germany, 2 , Fraunhofer-Institut für Silicatforschung, Würzburg Germany

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10:45 AM - S1.5
Oxygen Exchange Kinetics of Epitaxial PrBaCo2O5+x and LaBaCo2O5+x Thin Films.

Xuening Jiang 1 , Shuangyan Wang 1 , Guntae Kim 1 , Jian Liu 2 , M. Liu 2 , Wenquan Gong 1 , Chonglin Chen 2 , Allan Jacobson 1
1 Chemistry, University of Houston, Houston, Texas, United States, 2 Physics, University of Texas at San Antonio, San Antonio, Texas, United States

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11:00 AM - S1:mSOFCs
BREAK

11:30 AM - **S1.6
Micro-Solid Oxide Fuel Cells: From Thin Films to Power Delivering Membranes.

Jennifer L.M. Rupp 1 , Anja Bieberle-Huetter 1 , Anna Evans 1 , Henning Galinski 1 , Ashley Harvey 1 , Thomas Ryll 1 , Barbara Scherrer 1 , Rene Tolke 1 , Ludwig Gauckler 1
1 Nonmetallic Inorganic Materials, ETH Zurich, Zurich Switzerland

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12:00 PM - S1.7
Deposition of a Proton Conductive Oxide Thin Film on a Porous Stainless Steel Substrate using Liquid Delivery MOCVD.

Kiyoshi Uchiyama 1 , Hiroyuki Sakairi 1 , Hiroshi Ichise 1 , Gakuko Lin 1 , Tadashi Shiosaki 1 , Hiroki Ikeda 2 , Katsu Yanagimoto 2 , Akira Nakayama 3 4 , Yoji Yamada 3
1 School of Materials Science, Nara Institute of Science and Technology, Ikoma, Nara, Japan, 2 , Sanyo Special Steel, Himeji Japan, 3 , Ion Engineering Research Institute, Hirakata Japan, 4 , Osaka Scienece & Technology Center, Osaka Japan

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12:15 PM - S1.8
Microstructure and Electrochemical Properties of Epitaxial Samarium Doped Ceria (SDC)-SrTiO3 (STO) Buffered-MgO Films by Pulsed Laser Deposition.

Simone Sanna 1 2 , Vincenzo Esposito 1 , Silvia Licoccia 1 , Giuseppe Balestrino 2 , Enrico Traversa 1
1 NAST Center & Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, Rome Italy, 2 INFM – CNR Coherentia and Dipartimento di Ingegneria Meccanica, Università di Roma Tor Vergata, Rome Italy

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12:30 PM - S1.9
Sol-gel and PLD Preparation of Lanthanum Gallate-based Mixed Ionic-electronic Conducting Oxides.

Natalia Golubko 2 , Galina Kaleva 2 , Yuliana Roginskaya 2 , Sergey Kabanov 2 , Alexander Avetisov 2 , Gunnar Suchaneck 1 , Ekaterina Politova 2
2 , L.Y.Karpov Institute of Physical Chemistry, Moscow Russian Federation, 1 Solid State Electronics Lab, TU Dresden, Dresden Germany

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12:45 PM - S1.10
Enhanced Oxide Ion Conductivity at (Y2O3)x(ZrO2)1-x /SrTiO3 Ultra Thin-Film Epitaxial Heterostructures.

Javier Garcia-Barriocanal 1 , Alberto Rivera-Calzada 1 , Maria Varela 3 , Zouhair Sefrioui 1 , Enrique Iborra 2 , Carlos Leon 1 , Steve Pennycook 3 , Jacobo Santamaria 1
1 Dpto. Fisica Aplicada III, Universidad Complutense Madrid, Madrid Spain, 3 Materials Science & Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, United States, 2 Escuela Técnica Superior de Ingenieros de Telecomunicaciones, Universidad Politécnica de Madrid, Madrid Spain

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S2: Modelling and Fundamental Studies
Session Chairs
Dane Morgan
Steve Visco
Monday PM, December 01, 2008
Back Bay A (Sheraton)

2:30 PM - **S2.1
Solid State NMR Studies of Lanthanum Gallate Solid Electrolytes: Ion Mobility and Trapped Defects.

Frederic Blanc 1 , John Palumbo 1 , Clare Grey 1
1 Chemistry, Stony Brook University, Stony Brook , New York, United States

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3:00 PM - S2.2
Influence of the Chemical Strain Effect on the Lattice Parameter of Ce0.8Gd0.2O1.9.

Anna Kossoy 1 , Isai Feldman 2 , Roman Korobko 1 , Ellen Wachtel 2 , Joachim Maier 3 , Igor Lubomirsky 1
1 Department of Materials and Interfaces, Weizmann Institute of Science, Rehovot Israel, 2 Department of Chemical Research Support, Weizmann Institute of Science, Rehovot Israel, 3 , Max Planck Institute for Solid State Research, Stuttgart Germany

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3:15 PM - S2.3
First-Principles Study of ZrO2 – In2O3 Heterointerface Structure and Properties.

Hakim Iddir 1 , Peter Zapol 1 , Fong Dillon 1 , Paul Fuoss 1 , Jeffrey Eastman 1
1 Materials Science Division, Argonne National Laboratory, Argonne, Illinois, United States

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3:30 PM - S2.4
Examination of the LaFeO3 (010) Surface using Density Functional Theory and Thermodynamics.

Chan-Woo Lee 1 , Eric Wachsman 1 , Simon Phillpot 1 , Ram Devanathan 2 , Susan Sinnott 1
1 Department of Materials Science and Engineering, University of Florida, Gainesville, Florida, United States, 2 Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, United States

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3:45 PM - S2.5
Ab initio Thermokinetic Modeling of Defect Chemistry, Oxygen Transport, and Surface Oxygen Reduction Reactions for (La,Sr)MnO3 for Solid Oxide Fuel Cells.

Yueh-Lin Lee 1 , Dane Morgan 1
1 Materials Science Program, University of Wisconsin-Madison, Madison, Wisconsin, United States

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4:00 PM - *
Break

4:30 PM - S2.6
First-principles and CALPHAD Thermodynamic Modeling of Defects in La1-xSrxCoO3-δ.

James Saal 1 , Mei Yang 1 , Venkateswara Rao Manga 1 , Zi-Kui Liu 1
1 Materials Science and Engineering, Penn State University, University Park, Pennsylvania, United States

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4:45 PM - S2.7
Computing Electrochemical Impedance of Solid Electrolyte from Fluctuations.

Eunseok Lee 1 , Wei Cai 1 , Fritz Prinz 1 2
1 Mechanical Engineering, Stanford University, Stanford, California, United States, 2 Materials Science and Engineering, Stanford University, Stanford, California, United States

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5:00 PM - S2.8
Thermodynamics and Kinetics of Conversion Reaction Cathodes from First Principles.

Robert Doe 1 , Kristin Persson 1 , Gerbrand Ceder 1
1 Dept. of Materials Science & Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, United States

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5:15 PM - S2.9
DFT-based Design of Orthosilicate-based Cathode Materials for Li Ion Batteries.

Anti Liivat 1 , Kinson Kam 1 , John Thomas 1
1 Materials Chemistry, Uppala University, Uppsala Sweden

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5:30 PM - S2.10
Polyatomic Anions as Mobile Species in Solid Electrolytes.

Stefan Adams 1 , Yongkai Zhou 1 , R. Prasada Rao 1 , Arkady Neiman 2 , Doreen Edwards 3
1 Mater. Science and Eng. , Nat. University of Singapore, Singapore Singapore, 2 Chemical Department, Ural State University, Ekaterinburg Russian Federation, 3 Inamori School of Engineering , Alfred University, Alfred, New York, United States

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5:45 PM - S2.11
Point Defect Mediated Cation Transport in MgAl2O4.

Samuel Murphy 1 , Blas Uberuaga 2 , Kurt Sickafus 2 , Roger Smith 3 , Robin Grimes 1
1 Materials, Imperial College London, London United Kingdom, 2 , Los Alamos National Laboratory, Los Alamos, New Mexico, United States, 3 Mathematical Sciences, Loughborough University, Loughborough United Kingdom

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S3: Poster Session: Batteries
Session Chairs
Tim Armstrong
Toshiaki Matsui
Rosa Palacin
Enrico Traversa
Tuesday AM, December 02, 2008
Exhibition Hall D (Hynes)

9:00 PM - S3.1
Silicon Cobalt Graphite Composite as the Anode Materials of Lithium Ion Secondary Batteries.

Jian Hong 1 , Stanley Whittingham 1
1 , State University of New York at Binghamton, Binghamton, New York, United States

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9:00 PM - S3.10
New Polymeric Electrolytes with Titanium Oxide as Inert Fillers Prepared by Sol-gel Technique.

Liliana Hechavarria 1 , Narcizo Mendoza 1 , Hailin Hu 1 , Jose Campos 1
1 Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, Temixco, Morelos, Mexico

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9:00 PM - S3.11
Component Diffusion in the Miscible Polymer Blend of PEGDME and PMMA Doped with LiTFSI Measured by Multinuclear PFG NMR.

Yan Meng 1 , Luis Smith 1
1 Carlson School of Chemistry and Biochemistry, Clark University, Worcester, Massachusetts, United States

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9:00 PM - S3.12
Atomistic Studies of Ionic Diffusion in Lithium Aluminosilicate.

Alexander Chroneos 1 2 , Hartmut Bracht 2 , Robin Grimes 1 , Andre Schirmeisen 3 , Bernhard Roling 4
1 Department of Materials, Imperial College London, London United Kingdom, 2 Institut für Materialphysik and Collaborative Research Centre (SFB 458), Westfälische Wilhelms-Universität Münster, Münster Germany, 3 Centre for Nanotechnology (CeNTech) and Collaborative Research Centre (SFB 458), Westfälische Wilhelms-Universität Münster, Münster Germany, 4 Fachbereich Chemie, Philipps-Universität Marburg, Marburg Germany

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9:00 PM - S3.14
Synthesis of Mesoporous Manganese Oxide with a High Surface Area.

Akira Endo 1 , Bao Wang Lu 1 , Takao Ohmori 1 , Keigo Matsuda 2
1 Research Institute for Innovation in Sustainable Chemistry, National Institute of Advance Industrial Science and Techology (AIST), Tsukuba, Ibaraki, Japan, 2 Department of Chemistry and Chemical Engineering, Yamagata University, Yamagata, Yamagata, Japan

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9:00 PM - S3.15
Transmission Electron Microscopy Observation of Li Extraction/insertion Behaviors in Li1.2Mn0.4Fe0.4O2 Positive Electrode Material for Li-ion Battery.

Jun Kikkawa 1 , Tomoki Akita 1 , Mitsuharu Tabuchi 1 , Masahiro Shikano 1 , Kuniaki Tatsumi 1 , Masanori Kohyama 1
1 Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology, Ikeda, Osaka, Japan

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9:00 PM - S3.16
Structural and Electrochemical Studies of Chemical Solution Derived xLiMn2O3-(1-x)Li[Mn0.5Ni0.5]O2 Cathodes.

Naba Karan 1 , Dillip Pradhan 1 , Jose Saavedra-Arias 1 , Reji Thomas 1 , Ram Katiyar 1
1 Physics, University of Puerto Rico, San Juan, Puerto Rico, United States

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