April 7 - 11, 2025
Seattle, Washington
Symposium Supporters
2025 MRS Spring Meeting & Exhibit
EL11.08.07

Materials Science/Device Technology for Integrated Super High K Dielectric Oxide Nanolaminates Crystalline Diamond for New Generation High Power Electronics

When and Where

Apr 10, 2025
11:00am - 11:15am
Summit, Level 4, Room 435

Presenter(s)

Co-Author(s)

Orlando Auciello1,2,Geunhee Lee3,Jiangwei Liu Liu4,Yasuo Koide4

The University of Texas at Dallas1,Original Biomedical Implants2,CVE Technology3,National Institute for Materials Science4

Abstract

Orlando Auciello1,2,Geunhee Lee3,Jiangwei Liu Liu4,Yasuo Koide4

The University of Texas at Dallas1,Original Biomedical Implants2,CVE Technology3,National Institute for Materials Science4
This abstract focus on describing the fundamental and applied materials science and device engineering to develop a new generation of transformational high power electronics based on the integration of novel multifunctional nanolaminate oxides thin films with super high dielectric constant, and single crystal diamond. Specific research and devoce evelopment to be discussed include:
Materials Science performed to develop transformational TiOx/Al2O3 nanolaminates, exhibiting giant dielectric constant (up to k=1000), low leakage current (10-8 - 10-9 A/cm2, and low losses
(tan d = 0.04), induced by a nanoscale thick Al2O3 layer at the top electrode nanolaminate interface. The information to be presented will include discussion of the physics responsible for the giant dielectric constant, underlined by the Maxwell-Wagner relaxation mechanism, whereby the dielectric constant is controlled by oxygen vacancies at the nanolaminate interfaces.
Materials science and device design performed to integrate the high K dielectric nanolaminates on single crystal diamond to fabricate the first integrated TiOx/Al2O3 nanolaminates single crystal diamond based Metal Organic Semiconductor Field Effect Transistor devices.
Development of the lithography and RIE process to fabricate diamond-based nanoelectronic devices with integrated high K dielectric TiOx/Al2O3 nanolaminates single crystal H diamond surface terminated substrate, and measurement of electrical performance of first demonstrated Metal Organic Semiconductor Field Effect Transistor devices, which showed very good promising results.
The presentation will include a discussion of materials science issues that need to be addressed to optimize the performance of future TiOx/Al2O3 nanolaminates single crystal diamond based nanoelectronic devices, and investigate new HfO2/TiOx nanolaminates, involving the key HfO2 used in gates of current commercial Si-based micro/nano-electronic devices.

Keywords

atomic layer deposition | diamond | dielectric properties

Symposium Organizers

Robert Kaplar, Sandia National Laboratories
Filip Tuomisto, University of Helsinki
Motoaki Iwaya, Meijo University
Sriram Krishnamoorthy, University of California, Santa Barbara

Symposium Support

Silver
Taiyo Nippon Sanso

Session Chairs

Masataka Higashiwaki
Sriram Krishnamoorthy

In this Session