April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)

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2024 MRS Spring Meeting
EN10.08.07

Exploring The Relationship between The Local Structure of Lead Halide Perovskites and Their Macroscopic Properties

When and Where

Apr 24, 2024
11:45am - 12:00pm
Room 334, Level 3, Summit

Presenter(s)

Co-Author(s)

Milos Dubajic1,James Neilson2,Stephen Bremner3,Aron Walsh4,Michael Nielsen3,Samuel Stranks1

University of Cambridge1,Colorado State University2,UNSW Sydney3,Imperial College London4

Abstract

Milos Dubajic1,James Neilson2,Stephen Bremner3,Aron Walsh4,Michael Nielsen3,Samuel Stranks1

University of Cambridge1,Colorado State University2,UNSW Sydney3,Imperial College London4
Characterised by their exceptional optoelectronic characteristics, hybrid halide perovskites have gained prominence as a viable class of materials for energy conversion applications. Their marked impact is especially noticeable in the field of solar cell technology, where they have demonstrated substantial progress in efficiency. Despite these advancements, fully decoding their unique properties continues to pose a scientific enigma. Of particular interest is the local structure of these materials, which often diverges from their average configuration, and is hypothesised to be a significant determinant of their macroscopic properties.<br/><br/>We employed temperature-dependent diffuse X-ray scattering on a series of perovskite single crystals, enabling us to accurately characterise the local structure in real-space across all crystallographic phases of these perovskites. By developing a simple, computationally inexpensive model that accurately mirrors the experimental diffuse scattering, we were able to gain insights into how the local structure can be modulated through the substitution of A and X-site cations.<br/><br/>By employing a variety of optical microscopy techniques on identical compositions, we established a direct correlation with the emergence of ferroelastic properties in these materials.<br/><br/>Our study thereby underscores the critical role of compositional engineering in tailoring the local structure and, by extension, the macroscopic properties of hybrid halide perovskites.

Keywords

neutron scattering | phase transformation | x-ray diffraction (XRD)

Symposium Organizers

Ivan Mora-Sero, Universitat Jaume I
Michael Saliba, University of Stuttgart
Carolin Sutter-Fella, Lawrence Berkeley National Laboratory
Yuanyuan Zhou, Hong Kong University of Science and Technology

Symposium Support

Silver
Journal of Energy Chemistry

Session Chairs

Monica Morales-Masis
Carolin Sutter-Fella

In this Session