Apr 23, 2024
1:30pm - 2:00pm
Room 330, Level 3, Summit
Christina Birkel1,2,Rose Snyder1
Arizona State University1,Technische Universität Darmstadt2
Christina Birkel1,2,Rose Snyder1
Arizona State University1,Technische Universität Darmstadt2
The synthesis of MAX phases and their two-dimensional siblings MXenes, especially when pushing beyond Ti-based compounds, is far from trivial. Our group uses diverse preparation techniques to access new versions of these intriguing types of materials, recent examples include Cr
2GaC in the shape of carbonaceous microwires,
1 hollow and full microspheres
2 as well as hitherto unknown carbonitride phases, such as Cr
2GaC
1-xN
x and V
2GaC
1-xN
x.
3 We specialize in non-conventional methods, such as sol-gel chemistry
4–6 and microwave heating
7 to synthesize the MAX phases.
In this talk, I will highlight two of our recent projects: (i) Our work on a unique “514” MAX phase (Mo
0.75V
0.25)
5AlC
4, its structural investigation and transition to the respective MXene including its electrocatalytic properties. (ii) The transition from a MAX-like “221” compound Mo
2Ga
2C to the fully exfoliated MXene Mo
2C
Tx as well as Mn-doped variants. All materials are structurally characterized by diffraction and microscopy techniques and a deeper understanding of their chemical composition, formation mechanism and stability is obtained through spectroscopy and thermogravimetric methods.