April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)
Symposium Supporters
2024 MRS Spring Meeting & Exhibit
NM01.02.01

Synthesis Science between MAX phases and MXenes

When and Where

Apr 23, 2024
1:30pm - 2:00pm
Room 330, Level 3, Summit

Presenter(s)

Co-Author(s)

Christina Birkel1,2,Rose Snyder1

Arizona State University1,Technische Universität Darmstadt2

Abstract

Christina Birkel1,2,Rose Snyder1

Arizona State University1,Technische Universität Darmstadt2
The synthesis of MAX phases and their two-dimensional siblings MXenes, especially when pushing beyond Ti-based compounds, is far from trivial. Our group uses diverse preparation techniques to access new versions of these intriguing types of materials, recent examples include Cr2GaC in the shape of carbonaceous microwires,1 hollow and full microspheres2 as well as hitherto unknown carbonitride phases, such as Cr2GaC1-xNx and V2GaC1-xNx.3 We specialize in non-conventional methods, such as sol-gel chemistry4–6 and microwave heating7 to synthesize the MAX phases.
In this talk, I will highlight two of our recent projects: (i) Our work on a unique “514” MAX phase (Mo0.75V0.25)5AlC4, its structural investigation and transition to the respective MXene including its electrocatalytic properties. (ii) The transition from a MAX-like “221” compound Mo2Ga2C to the fully exfoliated MXene Mo2CTx as well as Mn-doped variants. All materials are structurally characterized by diffraction and microscopy techniques and a deeper understanding of their chemical composition, formation mechanism and stability is obtained through spectroscopy and thermogravimetric methods.

Keywords

chemical synthesis | nanoscale | x-ray diffraction (XRD)

Symposium Organizers

Stefano Ippolito, Drexel University
Michael Naguib, Tulane University
Zhimei Sun, Beihang University
Xuehang Wang, Delft University of Technology

Symposium Support

Gold
Murata Manufacturing Co., Ltd.

Silver
INNOMXENE Co.,Ltd.

Bronze
Energy Advances
Progress in Materials Science The Institution of Engineering and Technology (IET)

Session Chairs

Stefano Ippolito
Michael Naguib

In this Session