Enhancing Tin Dioxide Anode Performance by Narrowing the Potential Range and Optimizing Electrolytes

Tin dioxide (SnO₂) is a low-cost and high-capacity anode material for lithium-ion batteries, but the fast capacity fading significantly limits its practical applications. Current research efforts have focused on preparing sophisticated composite structures or optimizing functional binders, both of which increase material manufacturing costs. Herein, we utilize pristine and commercially available SnO₂ nanopowders and enhance their cycling performance by simply narrowing the potential range and optimizing electrolytes. Specifically, a narrower potential range (0-1 V) mitigates the capacity fading associated with the conversion reaction, whereas an ether-based electrolyte further suppresses the volume expansion related to alloy reaction. Consequently, this SnO₂ anode delivers a promising battery performance, with a high capacity of ~650 mAhg^-1 and stable cycling for 100 cycles. Our work provides an alternative approach to develop high-capacity and long-cycling metal oxide anode materials.