Degenerately Doped Thermally Stable 2D Transistors with Low Contact Resistance

High contact resistance has been a bottleneck in developing high-performance transition metal dichalcogenide (TMD) based p-type transistors. We report degenerately doped few-layer WSe₂ transistors with contact resistance as low as 0.23 ± 0.07 kΩ●μm per contact by using platinum (IV) chloride (PtCl₄) as the p-type dopant, which is composed of ions compatible with the complementary metal-oxide-semiconductor (CMOS) fabrication process. Top-gated devices with a gate length of 200 nm showed good switching behaviors implying that the dopant diffusion into the gate stack is not significant. The devices showed nearly identical performance after being kept in air for 86 days without any encapsulation while retaining the degenerately doped states at 78 K with pressure lower than 10^-5 Torr as well as temperatures over 300 °C highlighting the stability of the dopants. The presented method sets forth the availability of highly stable methods for pattern doping the transistors with thinned Schottky barrier width for low contact resistance devices.