April 7 - 11, 2025
Seattle, Washington
Symposium Supporters
2025 MRS Spring Meeting & Exhibit
QT01.01.03

Scalable Etchant-Free Transfer Technique for Low-Dimensional Materials from Metal Thin Film Surfaces

When and Where

Apr 10, 2025
9:00am - 9:15am
Summit, Level 4, Room 440

Presenter(s)

Co-Author(s)

Kentaro Yumigeta1,Muhammed Yusufoglu1,Franco Daluisio1,Richard Holloway1,Zafer Mutlu1

The University of Arizona1

Abstract

Kentaro Yumigeta1,Muhammed Yusufoglu1,Franco Daluisio1,Richard Holloway1,Zafer Mutlu1

The University of Arizona1
Graphene nanoribbons (GNRs) are quantum materials with tunable bandgap and electronic properties that depend strongly on ribbon width and edge structures, making them promising candidates for future electronics, particularly as channel materials in field-effect transistors (FETs). A bottom-up approach allows for atomic-level control of GNR structure and edge configuration through a catalytic reaction on metal surfaces, typically gold. To integrate GNRs into devices, they must be transferred from gold to insulating substrates. Current methods, involving gold film etching or polymer-assisted electrochemical transfer from bulk gold, face challenges such as potential damage, contamination by etchants, and limited scalability. We propose a new technique to transfer GNRs from large area gold thin films without etchants by using low melting point alloys. This method involves depositing GNRs on a gold film, supporting them with a polymer layer, and placing them onto molten alloy for electrochemical transfer. The alloy serves as an anode during the process to detach the polymer and GNRs from the gold film for transfer onto desired substrates, followed by polymer removal. This research advances GNR transfer techniques and offers scalable solutions for various low-dimensional materials. The method is applicable not only to carbon-based materials but also to transition metal dichalcogenides (TMDs), MXenes, hexagonal boron nitride (hBN), and other 2D materials obtained from metal solid solutions.

Keywords

graphene

Symposium Organizers

Andrew Mannix, Stanford University
Suji Park, Brookhaven National Laboratory
Dharmraj Kotekar Patil, University of Arkansas
Amirhossein Hasani, Montana State University

Symposium Support

Bronze
MonArk NSF Quantum Foundry - Montana State University
MonArk NSF Quantum Foundry- University of Arkansas
QUANTUM DESIGN

Session Chairs

Amirhossein Hasani
Dharmraj Kotekar Patil

In this Session