April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)

Event Supporters

2024 MRS Spring Meeting
EL05.10.02

A Method for Extracting 2D Semiconductor Mobility in Transistors with Gate-Voltage-Dependent Contact Resistance

When and Where

Apr 25, 2024
10:45am - 11:00am
Room 344, Level 3, Summit

Presenter(s)

Co-Author(s)

Robert Bennett1,Lauren Hoang1,Connor Cremers1,Andrew Mannix1,2,Eric Pop1

Stanford University1,Stanford Institute for Materials and Energy Sciences2

Abstract

Robert Bennett1,Lauren Hoang1,Connor Cremers1,Andrew Mannix1,2,Eric Pop1

Stanford University1,Stanford Institute for Materials and Energy Sciences2
Emerging two-dimensional (2D) semiconductors are frequently characterized in terms of their electron and hole mobilities, which quantitatively describe the speed at which these carriers move through a material under an applied electric field. These mobilities are commonly extracted by fabricating and measuring field-effect transistors (FETs) and applying one of several techniques to estimate the 2D semiconductor’s electron or hole mobility. Back-gated FETs are often used for these extractions because they can be fabricated in fewer steps and in higher yields compared to top- or dual-gated geometries. However, back-gated FETs experience <i>contact gating</i>:<i> </i>the<i> </i>electric field from the gate electrode acts on the transistor’s source and drain, causing the contact resistance to decrease as the magnitude of the gate voltage increases [1–5].<br/><br/>Although contact gating increases the drive current that a 2D FET can achieve by minimizing contact resistance in the on-state [1, 3, 6], contact gating also modifies the shape of a transistor’s transfer characteristics (i.e., <i>I</i><sub>D</sub> vs. <i>V</i><sub>GS</sub> characteristics, where <i>I</i><sub>D</sub> is the drain current and <i>V</i><sub>GS</sub> is the gate-to-source voltage). Consequently, conventional mobility extraction techniques can overestimate the mobilities of emerging semiconductors in back-gated FETs by up to an order of magnitude [2–4]. Thus, it was suggested that mobility in back-gated FETs should be estimated only at high |<i>V</i><sub>GS</sub>| (&gt;&gt; |<i>V</i><sub>T</sub>|, the threshold voltage) to ensure that the channel resistance, rather than contact gating, dominates the FET transfer characteristics [2, 4]. Alternatively, mobility can be accurately extracted from FETs with more complicated geometries and fabrication procedures that allow for the effects of contact gating to be eliminated (such as FETs that incorporate additional terminals to probe the channel [7]). Although these approaches may be viable in some situations, the former method can be unsuitable for transistors that experience early dielectric breakdown, whereas the latter approach can introduce additional experimental complexity during fabrication.<br/><br/>In this work, we propose a method of extracting a semiconductor’s carrier mobility that is compatible with back-gated FETs but that does not require the FET to operate in a channel-dominated regime. This method is inspired by the conventional transfer length method (TLM) approach but makes use of a transistor’s <i>I</i><sub>D</sub> vs. <i>V</i><sub>DS</sub> characteristics (where <i>V</i><sub>DS</sub> is the drain-to-source voltage), rather than its <i>I</i><sub>D</sub> vs. <i>V</i><sub>GS</sub> characteristics, allowing us to properly account for contact gating in back-gated FETs without having to use complicated geometries to directly probe the channel.<br/><br/>We validate this proposed method using current-voltage characteristics simulated by technology computer-aided design (TCAD). We find that this proposed method offers accurate mobility extraction (&lt; 10% error) in regimes where conventional methods (including the linear extrapolation method, Y-function method, and TLM approach) overestimate mobility by &gt; 50%. Furthermore, we demonstrate that this proposed method is robust to random variation in material quality, and we experimentally validate this method by demonstrating that experimentally-measured current-voltage characteristics of back-gated monolayer tungsten disulfide (WS<sub>2</sub>) FETs fit the method well. Overall, we anticipate that the method we propose in this work will allow for the mobilities of emerging semiconductors to be more quickly and easily extracted without requiring sophisticated transistor geometries or complicated fabrication procedures.<br/><br/><b>References:</b><br/><br/>[1] Z. Cheng <i>et al.</i>, <i>Nat. Electronics</i>,<i><b> </b></i><b>5, </b>416 – 423 (2022)<br/>[2] E. Bittle <i>et al.</i>, <i>Nat. Comm.,</i> <b>7</b>, 10908 (2016)<br/>[3] J. Nasr <i>et al.</i>, <i>Adv. Mater.,</i> <b>31</b>, 1806020 (2018)<br/>[4] I. McCulloch <i>et al.</i>, <i>Science</i>,<b> 352</b>,<b> </b>1521 – 1522 (2016)<br/>[5] W. Liu <i>et al.</i>, <i>ACS Nano</i>, <b>9</b>, 7904 – 7912 (2015)<br/>[6] G. Arutchelvan <i>et al.</i>, <i>Nanoscale</i>, <b>9</b>, 10869 – 10879 (2017)<br/>[7] C. Pang <i>et al.</i>, <i>Small</i>, <b>17</b>, 2100940 (2021)

Keywords

2D materials | electrical properties

Symposium Organizers

Silvija Gradecak, National University of Singapore
Lain-Jong Li, The University of Hong Kong
Iuliana Radu, TSMC Taiwan
John Sudijono, Applied Materials, Inc.

Symposium Support

Gold
Applied Materials

Session Chairs

Kah-Wee Ang
Andras Kis

In this Session