April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)
Symposium Supporters
2024 MRS Spring Meeting
EL06.09.01

Dynamic Processes of Oxygen Ion Exchange in Strontium Cobaltite Bilayer Thin Films Driven by Oxidation and Reduction

When and Where

Apr 26, 2024
8:30am - 8:45am
Room 343, Level 3, Summit

Presenter(s)

Co-Author(s)

Jill Wenderott1,2,Eric Dufresne1,Yan Li1,Hui Cao1,Qingteng Zhang1,Narayanachari Kondapalli3,D. Bruce Buchholz3,Supratik Guha4,1,Dillon Fong1

Argonne National Laboratory1,Drexel University2,Northwestern University3,The University of Chicago4

Abstract

Jill Wenderott1,2,Eric Dufresne1,Yan Li1,Hui Cao1,Qingteng Zhang1,Narayanachari Kondapalli3,D. Bruce Buchholz3,Supratik Guha4,1,Dillon Fong1

Argonne National Laboratory1,Drexel University2,Northwestern University3,The University of Chicago4
Transition metal oxides (TMOs) possess variable oxygen stoichiometry which can be the cause of distinct changes to physical and electronic properties. As an example, the well-studied TMO strontium cobaltite (SrCoO<sub>x</sub>), has two structurally and electrically distinct phases – the insulating orthorhombic brownmillerite (SrCoO<sub>2.5 </sub>– BM-SCO) and conducting cubic perovskite (SrCoO<sub>3-δ </sub>– PV-SCO) – that reversibly transition via a topotactic pathway with the insertion or removal of oxygen. In the thin film form, this topotactic transition occurs while preserving high quality epitaxial films, making this material system of interest for ionotronic devices. Here, BM-SCO/PV-SCO (001) (15 nm/15 nm) heterostructures on strontium titanate (STO) (001) and the exchange of oxygen ions across this bilayer are investigated in order to understand changes to the interface under oxidizing and reducing conditions.[1] X-ray diffraction (XRD) and X-ray photon correlation spectroscopy (XPCS) studies reveal strongly asymmetric behavior with slower dynamics appearing during reducing versus oxidizing conditions and similar dynamics in the SrCoO<sub>2.5</sub> layer as compared to those near the heterointerface. Our results demonstrate a stable and reversible heterointerface, showcasing SrCoO<sub>x</sub> as a model system for study of ionotronic behavior.<br/><br/>*Work supported by the Department of Energy, Office of Science, Basic Energy Sciences under contract no. DE-AC02-06CH11357.<br/>[1] Wenderott, et al. Adv. Mater. Interfaces 2023, 10, 2300127.

Keywords

epitaxy | ion-solid interactions | oxide

Symposium Organizers

Aiping Chen, Los Alamos National Laboratory
Woo Seok Choi, Sungkyunkwan University
Marta Gibert, Technische Universität Wien
Megan Holtz, Colorado School of Mines

Symposium Support

Silver
Korea Vacuum Tech, Ltd.

Bronze
Center for Integrated Nanotechnologies, Los Alamos National Laboratory
Radiant Technologies, Inc.

Session Chairs

Aiping Chen
Sundar Kunwar

In this Session