April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)

Event Supporters

2024 MRS Spring Meeting
EL05.14.02

Charge Carrier Balance in Scalable TMDC-Based Light Emitting Devices

When and Where

Apr 26, 2024
1:45pm - 2:00pm
Room 344, Level 3, Summit

Presenter(s)

Co-Author(s)

Tobiloba Fabunmi1,Henrik Myja1,Annika Grundmann2,Kalisch Holger2,Andrei Vescan2,Michael Heuken3,Tilmar Kümmell1,Gerd Bacher1

University of Duisburg-Essen1,RWTH Aachen University2,AIXTRON SE3

Abstract

Tobiloba Fabunmi1,Henrik Myja1,Annika Grundmann2,Kalisch Holger2,Andrei Vescan2,Michael Heuken3,Tilmar Kümmell1,Gerd Bacher1

University of Duisburg-Essen1,RWTH Aachen University2,AIXTRON SE3
2-dimensional transition metal dichalcogenides (TMDCs) such as WS<sub>2 </sub>are ultrathin materials with huge oscillator strength, strong in-plane bonds, and in the case of monolayers a direct bandgap. These outstanding properties have stimulated the development of various concepts for light emitting devices [1], often based on micrometer-sized flakes. Recently, a scalable device architecture has been suggested, where wafer-scale TMDCs grown by metal-organic chemical vapor deposition (MOCVD) have been embedded between electron and hole supporting layers to form a vertical p-i-n architecture [2-4].<br/> However, the luminance of TMDC-based LEDs in cw operation at room temperature is still limited to 50 cd/m<sup>2</sup>for microscale LEDs based on mechanically exfoliated WS<sub>2</sub> [5] and to about 1 cd/m<sup>2</sup> for scalable, 6 mm<sup>2</sup> large devices [2], respectively. One key requirement for optimizing the luminance is a balanced electron and hole injection into the active TMDC layer. In this work, we address the electron-hole balance in scalable WS<sub>2</sub>-based LEDs by systematically varying the architecture of electron injection layers (EIL). We fabricated three different LED archetypes: type 1 includes a ZnO EIL, type 2 contains Mg-doped ZnO as an EIL, and type 3 is a reference device without an EIL. At 5V forward bias, we observed a reduction of the current density by a factor of 10 in type 2 devices as compared to type 1. Simultaneously, the EQE was found to increase by an order of magnitude in the type 2 device compared to type 1, and a luminance of up to 3 cd/m<sup>2</sup> was obtained for type 2 devices. We attribute this to an improved electron-hole balance in type 2 devices, caused by a reduced efficiency of electron injection. Our interpretation is supported by device simulations using NextNano, which emphasizes the impact of a balanced electron and hole injection for efficient LEDs based on scalable 2D TMDCs.<br/><br/>References:<br/>[1] Jiang Pu et al. Adv. Mater. 30, 1707627 (2018)<br/>[2] D. Andrzejewski et al., ACS Photonics. 6, 1832-1839 (2019)<br/>[3] D. Andrzejewski et al., Adv. Opt. Mat. 8, 2000694 (2020)<br/>[4] H. Myja et al., Nanotechnology 34, 285201 (2023)<br/>[5] D. Andrzejewski et al., Nanoscale, 11, 8372–8379 (2019)

Symposium Organizers

Silvija Gradecak, National University of Singapore
Lain-Jong Li, The University of Hong Kong
Iuliana Radu, TSMC Taiwan
John Sudijono, Applied Materials, Inc.

Symposium Support

Gold
Applied Materials

Session Chairs

Salim El Kazzi
Silvija Gradecak
John Sudijono

In this Session