April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)
Symposium Supporters
2024 MRS Spring Meeting
EN09.03.05

Electrolyte-Assisted Polarization in BiFeO3/Nickel Foam for The Enhancement of Electrocatalytic Water Splitting

When and Where

Apr 23, 2024
4:00pm - 4:15pm
Room 337, Level 3, Summit

Presenter(s)

Co-Author(s)

Heng-Jui Liu1,Yue-Wen Fang2,Feng-Shuo Li1,Chih-Yen Chen3,Sheng-Zhu Ho4,Ching-Yu Chiang5,Yi-Chun Chen4

National Chung Hsing University1,University of the Basque Country2,Nation Yang Ming Chiao Tung University3,National Cheng Kung University4,National Synchrotron Radiation Research Center5

Abstract

Heng-Jui Liu1,Yue-Wen Fang2,Feng-Shuo Li1,Chih-Yen Chen3,Sheng-Zhu Ho4,Ching-Yu Chiang5,Yi-Chun Chen4

National Chung Hsing University1,University of the Basque Country2,Nation Yang Ming Chiao Tung University3,National Cheng Kung University4,National Synchrotron Radiation Research Center5
Efficient and long-lasting electrocatalysts with superior performance are essential for the efficient and sustainable production of green hydrogen, ensuring high yield and minimal energy consumption. Electrocatalysts based on transition metal oxides have a significant advantage due to their abundant natural resources, adjustable physical properties, and their compatibility with various solutions. Among the various oxide catalyst materials, ferroelectrics have received attention for their semiconducting properties and switchable spontaneous polarization, particularly as promising photoelectrodes in solar water splitting. However, their potential as electrocatalysts has been largely overlooked until now. Here we present an effective electrocatalytic electrode composed of a BiFeO<sub>3</sub>/nickel foam heterostructure. This heterostructure exhibits a lower overpotential and higher current density compared to a bare nickel foam electrode. Additionally, when in contact with an alkaline solution, the interaction between hydroxyls and the BiFeO<sub>3</sub> surface induces a significant area of upward self-polarization. This phenomenon reduces the adsorption energy of subsequent adsorbates and enhances the efficiency of the oxygen and hydrogen evolution reactions. Our work illustrates a unique approach, utilizing functional semiconducting materials for the development of highly efficient electrocatalytic electrodes.

Keywords

hydrothermal

Symposium Organizers

Christopher Barile, University of Nevada, Reno
Nathalie Herlin-Boime, CEA Saclay
Michel Trudeau, Concordia University
Edmund Chun Ming Tse, University Hong Kong

Session Chairs

Christopher Barile
Edmund Chun Ming Tse

In this Session