April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)
Symposium Supporters
2024 MRS Spring Meeting & Exhibit
MT02.09.01

Data-Driven Analysis on The Dynamics and Heterogeneity of Particle Network in Composite Electrodes of Li-Ion Batteries

When and Where

Apr 25, 2024
8:00am - 8:30am
Room 321, Level 3, Summit

Presenter(s)

Co-Author(s)

Kejie Zhao1

Purdue University1

Abstract

Kejie Zhao1

Purdue University1
We use a data-driven approach to assess the heterogeneous electrochemistry and mechanics in composite cathodes. We visualize the morphological defects at multi-scales ranging from the macroscopic composite, particle ensembles, to individual single particles. Particle fracture and interfacial debonding are identified in a large set of tomographic data. The mechanical damage of active particles is highly heterogeneous. The difference originates from the polarization of the electrolyte potential, various local conducting environments, and thus the non-uniform distribution of the activation energy for the charge transfer reaction. We model the kinetics of intergranular fracture and interfacial degradation to assess the heterogeneous mechanical damage in composite electrodes using microstructure-informed mechanics modeling. We quantify the influence of the mechanical damage on the metrics of battery performance. More interestingly, the interfacial failure reconstructs the conductive network and redistribute the electrochemical activities that render a dynamic nature of electrochemistry and mechanics evolving over time in the composite electrodes.

Keywords

multiscale

Symposium Organizers

Alejandro Franco, Universite de Picardie Jules Verne
Deyu Lu, Brookhaven National Laboratory
Dee Strand, Wildcat Discovery Technologies
Feng Wang, Argonne National Laboratory

Symposium Support

Silver
PRX Energy

Session Chairs

Eva Allen
Feng Wang

In this Session