Apr 23, 2024
5:00pm - 7:00pm
Flex Hall C, Level 2, Summit
Qifan Zheng1,Xinchao Wang1,Dakotah Thompson1
University of Wisconsin-Madison1
Qifan Zheng1,Xinchao Wang1,Dakotah Thompson1
University of Wisconsin-Madison1
The alkaline earth metal difluorides are critical optical components for applications in non-contact temperature sensors, thermal imaging, and infrared spectroscopy due to their characteristically low refractive index and wide optical transparency spanning the ultraviolet to mid-infrared. Despite their technological importance, a systematic investigation into the temperature dependence of their optical properties is lacking. In this study, spectroscopic ellipsometry was used to obtain the refractive index of monocrystalline CaF
2, BaF
2, and MgF
2 for wavelengths between 220 nm and 1700 nm, and for temperatures between 21 °C and 368 °C. The refractive index of CaF
2 and BaF
2 was observed to decrease linearly with increasing temperature, which can be largely attributed to a reduction in the mass density due to thermal expansion. In contrast, the refractive index of MgF
2 was found to vary nonlinearly with temperature, which suggests competing effects from the material’s electronic polarizability. The temperature-dependent refractive index data reported here provide a finely-resolved mapping of the thermo-optic coefficient for these three materials, which could inform the development of optical devices operating at elevated or unsteady temperatures.