Apr 23, 2024
5:00pm - 7:00pm
Flex Hall C, Level 2, Summit
Sang-Wook Han1,Eun-Suk Jeong1,In-Hui Hwang2
Jeonbuk National University1,Argonne National Laboratory2
Sang-Wook Han1,Eun-Suk Jeong1,In-Hui Hwang2
Jeonbuk National University1,Argonne National Laboratory2
The dispersion and stability of noble-metal catalysts on transition-metal-oxide supports are considerably important for practical applications of the catalysts. Pt nanoparticles are uniformly and highly dispersed on transition-metal oxides when hydrogen peroxide (H
2O
2) is applied before calcination at 500 <span style="font-size:10.8333px">
oC</span>
. The influence of H
2O
2 on the dispersion and the stability of Pt nanoparticles on titania-incorporated fumed silica (Pt/Ti-FS) supports was examined using in-situ X-ray absorption fine structure (XAFS) measurements at the Pt L
3 and Ti K edges as well as density functional theory (DFT) calculations. The local structural and chemical properties around Pt and Ti atoms of Pt/Ti-FS with and without H
2O
2 treatment were monitored using
in-situ XAFS during heating from room temperature to 500
oC. XAFS revealed that the Pt nanoparticles of H
2O
2-Pt/Ti-FS are highly stable and that the Ti atoms of H
2O
2-Pt/Ti-FS support form into a distorted-anatase TiO
2. DFT calculations showed that Pt atoms bond more stably to oxidized-TiO
2 surfaces than they do to bare- and reduced-TiO
2 surfaces. XAFS measurements and DFT calculations clarified that the presence of extra oxygen atoms due to the H
2O
2 treatment plays a critical role in the strong bonding of Pt atoms to TiO
2 surfaces.