April 22 - 26, 2024
Seattle, Washington
May 7 - 9, 2024 (Virtual)
Symposium Supporters
2024 MRS Spring Meeting & Exhibit
EN09.04.29

Dispersion and Stability Mechanism of Heterogeneous Catalysts

When and Where

Apr 23, 2024
5:00pm - 7:00pm
Flex Hall C, Level 2, Summit

Presenter(s)

Co-Author(s)

Sang-Wook Han1,Eun-Suk Jeong1,In-Hui Hwang2

Jeonbuk National University1,Argonne National Laboratory2

Abstract

Sang-Wook Han1,Eun-Suk Jeong1,In-Hui Hwang2

Jeonbuk National University1,Argonne National Laboratory2
The dispersion and stability of noble-metal catalysts on transition-metal-oxide supports are considerably important for practical applications of the catalysts. Pt nanoparticles are uniformly and highly dispersed on transition-metal oxides when hydrogen peroxide (H2O2) is applied before calcination at 500 <span style="font-size:10.8333px">oC</span>. The influence of H2O2 on the dispersion and the stability of Pt nanoparticles on titania-incorporated fumed silica (Pt/Ti-FS) supports was examined using in-situ X-ray absorption fine structure (XAFS) measurements at the Pt L3 and Ti K edges as well as density functional theory (DFT) calculations. The local structural and chemical properties around Pt and Ti atoms of Pt/Ti-FS with and without H2O2 treatment were monitored using in-situ XAFS during heating from room temperature to 500 oC. XAFS revealed that the Pt nanoparticles of H2O2-Pt/Ti-FS are highly stable and that the Ti atoms of H2O2-Pt/Ti-FS support form into a distorted-anatase TiO2. DFT calculations showed that Pt atoms bond more stably to oxidized-TiO2 surfaces than they do to bare- and reduced-TiO2 surfaces. XAFS measurements and DFT calculations clarified that the presence of extra oxygen atoms due to the H2O2 treatment plays a critical role in the strong bonding of Pt atoms to TiO2 surfaces.

Keywords

extended x-ray absorption fine structure (EXAFS)

Symposium Organizers

Christopher Barile, University of Nevada, Reno
Nathalie Herlin-Boime, CEA Saclay
Michel Trudeau, Concordia University
Edmund Chun Ming Tse, University Hong Kong

Session Chairs

Nathalie Herlin-Boime
Michel Trudeau
Edmund Chun Ming Tse

In this Session