December 1 - 6, 2024
Boston, Massachusetts

Event Supporters

2024 MRS Fall Meeting & Exhibit
CH05.16.01

Ultrafast Energy Transfer and Structural Dynamics of the PTB7 Polymer on a MoS2 Monolayer

When and Where

Dec 5, 2024
1:30pm - 1:45pm
Sheraton, Third Floor, Fairfax B

Presenter(s)

Co-Author(s)

Ming-Fu Lin1,Hung-Tzu Chang2,Andrew Attar3,Aravind Krishnamoorthy4,Alexander Britz1,Xiang Zhang5,Xiaozhe Shen1,Pulickel Ajayan5,Xijie Wang1,Priya Vashishta6,Aiichiro Nakano6,Uwe Bergmann7

SLAC National Accelerator Laboratory1,Max Planck Institute2,Vescent Photonics3,Texas A & M University4,Rice University5,University of Southern California6,University of Wisconsin-Madison7

Abstract

Ming-Fu Lin1,Hung-Tzu Chang2,Andrew Attar3,Aravind Krishnamoorthy4,Alexander Britz1,Xiang Zhang5,Xiaozhe Shen1,Pulickel Ajayan5,Xijie Wang1,Priya Vashishta6,Aiichiro Nakano6,Uwe Bergmann7

SLAC National Accelerator Laboratory1,Max Planck Institute2,Vescent Photonics3,Texas A & M University4,Rice University5,University of Southern California6,University of Wisconsin-Madison7
Energy transfer across a heterogeneous interface is an important topic to understand detailed functioning mechanisms of solar cells and photocatalysts. Here, we used mega-electronvolt ultrafast electron diffraction (MeV UED) as a sensitive time-resolved ”thermometer” to simultaneously measure structural dynamics and energy transfer between a polymer (PTB7) and an atomic thin MoS<sub>2</sub> monolayer. Optical excitation of the polymer to the excited state relaxes quickly through the heterojunction interface to the monolayer MoS2. The thermal energy transfers from the polymer to the atomic layer can be described by a thermal transport model. The time-resolved structural dynamics of polymer suggests a bond dissociation located specifically at the C-O sidechain during the flattening motion of the two aromatic conjugated rings in the excited state, providing the fundamental mechanism of the photo-instability of a polymer in the applications of solar cell materials.

Keywords

2D materials | Debye temperature

Symposium Organizers

Miaofang Chi, Oak Ridge National Laboratory
Ryo Ishikawa, The University of Tokyo
Robert Klie, University of Illinois at Chicago
Quentin Ramasse, SuperSTEM Laboratory

Symposium Support

Bronze
EKSPLA 
Protochips
Thermo Fisher Scientific, Inc.

Session Chairs

Ryo Ishikawa
Quentin Ramasse

In this Session