Towards a Universal Design Principle for Low-Hysteresis High-Valent Redox in Battery Cathodes—Synergizing Cationic Ordered Vacancies with Tunable Metal-Ligand Hybridization

Sodium-ion batteries have the potential to meet growing demand for energy storage due to their low costs stemming from natural resource abundances, but their cathode energy densities must be improved to be comparable to those of lithium-ion batteries. One strategy is accessing high voltage capacity through high-valent redox reactions. Such reactions usually cause instability in cathode materials, but Na₂Mn₃O₇ has demonstrated excellent performance and reversibility in the high-valent regime due to its unique lattice structure with ordered Mn vacancies. This work expands the universality of the ordered vacancy as a design principle and increases the material candidates with such exceptional electrochemical behavior. Our approach involves synergizing cationic ordered vacancies with tunable metal-ligand hybridization through partial metal substitution. The impact of substitution in the low- and high-valent regimes is investigated through advanced microscopy and in-situ synchrotron X-ray characterization techniques. Substitution leads to larger specific capacities, enhanced cycle stability, and superior rate performance. This study lays the foundation for developing new cathode materials with stable high-valent redox through substitution of redox-active transition metals by employing cationic ordered vacancies and partial transition metal substitution as design principles in tandem.