December 1 - 6, 2024
Boston, Massachusetts
Symposium Supporters
2024 MRS Fall Meeting & Exhibit
NM05.12.09

Novel One-Dimensional Lepidocrocite Titanium-Oxide Nanofilaments—Synthesis, Characterization and Superior Dye Adsorption Properties

When and Where

Dec 4, 2024
8:00pm - 10:00pm
Hynes, Level 1, Hall A

Presenter(s)

Co-Author(s)

Mohamed Ibrahim1,Gregory Schwenk1,Hussein Badr1,Adam Walter1,Michel Barsoum1

Drexel University1

Abstract

Mohamed Ibrahim1,Gregory Schwenk1,Hussein Badr1,Adam Walter1,Michel Barsoum1

Drexel University1
This study introduces a novel class of one-dimensional lepidocrocite titanium-oxide-based nanofilaments (1DLs), synthesized through a cost-effective and scalable solution-precipitation technique conducted under ambient conditions. The synthesis involves reacting titanium-based precursor powders, specifically TiB, TiC, Ti<sub>5</sub>Si<sub>3</sub>, or TiN, with quaternary ammonium hydroxide solutions, such as tetraethylammonium hydroxide (TEAH), tetrapropylammonium hydroxide (TPAH), and tetrabutylammonium hydroxide (TBAH), at 80°C over 3-4 days. X-ray diffraction, density functional theory, and transmission electron microscopy analyses revealed that the building blocks are 1D nanofilaments with cross-sectional dimensions of approximately 5×7 Å<sup>2</sup>. These nanofilaments stack along the [020] direction and grow along the [100] direction. They can form pseudo-2D structures when filtered or non-agglomerating semi-spherical and porous mesoporous particles (PMPs) upon washing and drying. The bandgap (BG) of these nanofilaments is high, ranging from 3.8 to 3.9 eV, due to size confinement. The pronounced adsorption capability of these nanofilaments was demonstrated by their ability to absorb and degrade organic dyes. For instance, in the case of Rhodamine 6G, TEA-1DL achieved up to a 65% reduction after 30 minutes in the dark, surpassing the performance of any existing TiO<sub>2</sub> materials.

Keywords

nanostructure | x-ray diffraction (XRD)

Symposium Organizers

Andras Kis, Ecole Polytechnique Federale de Lausanne
Li Lain-Jong, University of Hong Kong
Ying Wang, University of Wisconsin, Madison
Hanyu Zhu, Rice University

Session Chairs

Ying Wang
Hanyu Zhu

In this Session