December 1 - 6, 2024
Boston, Massachusetts
Symposium Supporters
2024 MRS Fall Meeting & Exhibit
EL05.08.04

Harnessing Stochasticity in 2D Materials—A First-Principles Study of Phonon-Assisted Defect Charge Dynamics in WS2

When and Where

Dec 4, 2024
8:00pm - 10:00pm
Hynes, Level 1, Hall A

Presenter(s)

Co-Author(s)

Chenmu Zhang1,Evgeni Penev1,Boris Yakobson1

Rice University1

Abstract

Chenmu Zhang1,Evgeni Penev1,Boris Yakobson1

Rice University1
Stochasticity plays an important role in cryptography, stochastic and neural-like computing, facilitating low-cost, error-tolerant solutions to complex problems such as integer factorization, invertible logic and optimization. Specifically, we investigate phonon-assisted defect charge dynamics in 2D materials, e.g. a sulfur vacancy in WS2 monolayer (VS-WS2), using first principles calculations [1]. We find that a true random bit generation scheme based on VS-WS2 optimally balances bitrate, energy efficiency, and tunability of bit probability. The entropy source based on VS-WS2 enables unbiased random bit generation at bitrates of 30 Mbps, which can be further optimized up to terabits per second by minimizing the energy barrier (Eb) for defect-to-band electron transition through 3% tensile strain of the host-material. Further advantages of VS-WS2 include a large current contrast between two states, significant tunability of bit probability, and reduced energy consumption. Furthermore, we explore the conditions needed to achieve a low Eb, unveiling new possibilities in 2D material-based entropy sources. The essential insights into phonon-assisted defect charge dynamics combines with practical designs for high-performance, energy-efficient stochastic devices.

Supported by the Office of Naval Research (N00014-22-1-2753)

[1] Chenmu Zhang, Evgeni S. Penev, Boris I. Yakobson. Exploring the limits of random bits generation in two-dimensional semiconductors from first principles. submitted (2024).

Keywords

electron-phonon interactions

Symposium Organizers

Paschalis Gkoupidenis, Max Planck Institute
Francesca Santoro, Forschungszentrum Jülich/RWTH Aachen University
Ioulia Tzouvadaki, Ghent University
Yoeri van de Burgt, Technische Universiteit Eindhoven

Session Chairs

Paschalis Gkoupidenis
Francesca Santoro

In this Session