Functionalized Graphene-Like Materials via a One Pot Reaction Enabling Pore Size and Functional Groups Modification

Graphene is a material characterized by its superior electrical conductivity and exceptional mechanical strength. However, post-reduction or functionalization processes typically result in a significant loss of these enhanced properties. In this work, we introduce a novel class of graphitic materials that exhibit tunable functionalities and pore sizes, excellent thermal stability and modifiable band gaps. These highly ordered Covalent Organic Frameworks (COFs) are synthesized via a Pictet-Spengler polymerization reaction.