Dec 3, 2024
4:30pm - 4:45pm
Hynes, Level 3, Ballroom B
Septia Kholimatussadiah1,Mohammad Qorbani1,Yu-Ling Liu1,Michitoshi Hayashi1,Kuei-Hsien Chen1,2,Li-Chyong Chen1
National Taiwan University1,Academia Sinica2
Septia Kholimatussadiah1,Mohammad Qorbani1,Yu-Ling Liu1,Michitoshi Hayashi1,Kuei-Hsien Chen1,2,Li-Chyong Chen1
National Taiwan University1,Academia Sinica2
Electron transfer plays a significant role in many biological and chemical processes, especially in the catalytic reactions involved in photoelectrochemical energy conversion and storage. Revealing the electron transfer behaviour at the interface of electrode-electrolyte is thus of great importance. Here, we fabricate atomically thin tungsten diselenide (WSe
2) by chemical vapor deposition method and directly map the outer-sphere and inner-sphere electron transfer using Atomic Force Microscopy combined with Scanning Electrochemical Microscopy (AFM-SECM). Using AFM-SECM, the topography of the sample as well as the mechanical, electrical, and electrochemical properties can be simultaneously obtained. AFM-SECM feedback mapping shows layer-dependent electrocatalytic ability of WSe
2 to oxidize the redox species Ru
2+ back to Ru
3+. Moreover, AFM-SECM substrate generation and tip collection mode show layer-dependent hydrogen evolution reaction of WSe
2. Compared with monolayer and bilayer, few-layer WSe
2 shows better stability in electrochemical environment, faster electron transfer, and higher hydrogen production. First principal calculations show that the layer-dependent electron transfer and hydrogen production is highly correlated with the higher electronic density of states and more suitable Fermi level position in few-layer WSe
2 for specific redox reactions. Furthermore, finite element method-based numerical simulations using MATLAB® and COMSOL Multiphysics® are performed to calculate the electron transfer rate constants
k0 and simulate the steady-state concentration gradient. Finally, the electrochemistry at WSe
2 electrode-electrolyte interface is spatially resolved at the nanoscale, and understanding this behaviour will be useful for future electrochemical devices.