December 1 - 6, 2024
Boston, Massachusetts
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2024 MRS Fall Meeting & Exhibit
PM03.07.04

Enhancing Ohmic Contacts in β-Ga2O3 via N2 Plasma Treatment

When and Where

Dec 4, 2024
8:00pm - 10:00pm
Hynes, Level 1, Hall A

Presenter(s)

Co-Author(s)

Junghun Kim1,Dongryul Lee2,Jihyun Kim3

Korea Electrotechnology Research Institute1,Samsung Electronics2,Seoul National University3

Abstract

Junghun Kim1,Dongryul Lee2,Jihyun Kim3

Korea Electrotechnology Research Institute1,Samsung Electronics2,Seoul National University3
β-Ga<sub>2</sub>O<sub>3</sub> has emerged as a highly promising material for next-generation power semiconductors due to its exceptional properties such as high theoretical breakdown field and Baliga's figure-of-merit. However, the performance of β-Ga<sub>2</sub>O<sub>3</sub>-based devices, including SBDs and MOSFETs, is often hindered by the presence of high contact resistance between the Ga<sub>2</sub>O<sub>3</sub> and metal contacts. This resistance limits device efficiency by increasing switching and conduction losses.<br/>Conventional methods for reducing contact resistance include: 1) rapid thermal annealing (RTA) to enhance interface defects between metal and semiconductor, and 2) ion implantation to increase doping concentration beneath metal contacts. However, post-metallization annealing (400–500°C) may lead to interfacial degradation, potentially restricting the front-end-of-line process for Ga<sub>2</sub>O<sub>3</sub>. Moreover, ion implantation for doping can cause damage to the semiconductor lattice.<br/>In this study, a novel annealing-free N<sub>2</sub> plasma treatment for achieving Ohmic contacts was demonstrated. This simple treatment successfully reduced the contact resistance to 13.1 kΩμm through a defect-compensating effect. X-ray photoelectron spectroscopy (XPS) was employed to verify the impact of N<sub>2</sub> plasma treatment on Ga<sub>2</sub>O<sub>3</sub> bonds, while Raman spectroscopy assessed the crystalline quality of the plasma-treated region. β-Ga<sub>2</sub>O<sub>3</sub> nanosheet FETs treated with N<sub>2</sub> plasma exhibited an impressive on/off ratio of ~10<sup>10</sup> and a field-effect mobility of 103.7 cm<sup>2</sup>/Vs. To validate the air-stability of the N<sub>2</sub> plasma-treated devices, electrical measurements were conducted seven days after fabrication. This work presents a robust method to reduce contact resistance using a simple process, pushing the boundaries of β-Ga<sub>2</sub>O<sub>3</sub> device performance.<br/><br/><b>This research was financially supported by the Korea Research Institute for Defense Technology Planning and Advancement (KRIT) grant funded by the Defense Acquisition Program Administration (DAPA) (KRIT-CT-22-046)</b>

Keywords

defects | interface | surface chemistry

Symposium Organizers

Rebecca Anthony, Michigan State University
I-Chun Cheng, National Taiwan University
Lorenzo Mangolini, University of California, Riverside
Davide Mariotti, University of Strathclyde

Session Chairs

Rebecca Anthony
Lorenzo Mangolini

In this Session