December 1 - 6, 2024
Boston, Massachusetts
Symposium Supporters
2024 MRS Fall Meeting & Exhibit
SF05.07.15

Stabilization of the Metastable SnXTi1-XO2 Alloy and Suppression of Its Spinodal Decomposition

When and Where

Dec 3, 2024
8:00pm - 10:00pm
Hynes, Level 1, Hall A

Presenter(s)

Co-Author(s)

Pritha Biswas1,Tamara Koledin1,Melissa Santala1,Janet Tate1

Oregon State University1

Abstract

Pritha Biswas1,Tamara Koledin1,Melissa Santala1,Janet Tate1

Oregon State University1
Among the bimetallic oxide alloys, spinodal decomposition of the SnO<sub>2</sub>-TiO<sub>2</sub> phase has garnered much attention due to its applications in gas sensors, photo anodes, and electron transport layers. The tin titanium oxide alloy usually undergoes spinodal decomposition at a critical temperature, exhibiting a characteristic lamellar microstructure upon decomposition. Unlike classical nucleation and growth, spinodal decomposition is a homogeneous phase transformation with no associated activation energy barrier. In this work, a non-decomposed, metastable Sn<sub>X</sub>Ti<sub>1−X</sub>O<sub>2</sub> thin film alloy with the Sn:Ti atomic ratio in the range of 62:38 to 78:22 was deposited from a mixed oxide target by controlling the partial pressure of oxygen, sputter power, and deposition time in a radio frequency sputter chamber. The crystalline phase of the oxide film was obtained upon subsequent annealing at 500°C. While the thermodynamic equilibrium solubility limit of TiO<sub>2</sub> in SnO<sub>2</sub> at 500°C is of the order of 10%, this thin film alloy demonstrated a substantially higher cationic substitution of Sn by Ti, approximately 38%, in Sn<sub>1-X</sub>Ti<sub>X</sub>O<sub>2</sub>, highlighting its metastability. These Sn<sub>1-X</sub>Ti<sub>X</sub>O<sub>2 </sub>thin film samples were annealed from 500°C to 1200°C in steps of 100°C, but there was no observable decomposition. According to the (SnO<sub>2</sub>-TiO<sub>2</sub>) phase diagram, a metastable (Sn,Ti)O<sub>2</sub> alloy with Sn:Ti in the range of 62:38 to 78:22 should decompose at a critical temperature in the range 1100°C – 1200°C. Stacking faults and other planar defects observed in cross-sectional TEM analysis point toward a complex intergrowth of SnO<sub>2</sub> and TiO<sub>2 </sub>which may suppress the decomposition and enhance the metastability window of the alloy to the temperature as high as1200°C.

Keywords

alloy | nanostructure | oxide

Symposium Organizers

Yoshisato Kimura, Tokyo Institute of Technology
Florian Pyczak, Helmholtz-Zentrum Hereon
Petra Spörk-Erdely, Graz University of Technology
Akane Suzuki, GE Aerospace Research

Symposium Support

Gold
GE Aerospace Research

Session Chairs

Yoshisato Kimura
Akane Suzuki

In this Session